Temperature, 2011, Vol. 49, No. 2, pp. 193–198. © Pleiades Publishing, Ltd.,
2011. Original Russian Text © A.E.
Galashev, O.R. Rakhmanova, O.A. Novruzova, 2011, published in Teplofizika
Vysokikh Temperatur, 2011, Vol. 49, No. 2, pp. 201–206.
Modeling of the Spectral Characteristics of the Ozone–Water Cluster System
A. E. Galashev, O. R.
Rakhmanova, and O. A. Novruzova
Abstract—The absorption of one to six ozone molecules by the
(H2O)25 cluster is studied by the method of molecular
dynamics under near-atmospheric conditions. The capture of O3 molecules
by a water cluster produces a decrease in the integrated intensity of IR absorbance,
reflectance, and Raman spectra. IR absorbance spectra are highly sensitive to
the number of ozone molecules absorbed by a water cluster. The observed photon
emission time and the radiation intensity of a dispersed aqueous system with
absorbed ozone molecules are appreciably reduced relative to the analogous
characteristics of a pure water cluster system.