IR Absorption, Reflection, and Emission Spectra of Aqueous Disperse Systems Interacting with Nitric Oxide
IR Absorption, Reflection, and Emission
Spectra
of Aqueous Disperse Systems Interacting
with Nitric Oxide
A. E. Galashev and O. R. Rakhmanova
Abstract
IR absorption, reflection, and emission
spectra of aqueous disperse systems that absorbed molecules of nitric oxide are calculated. In order
to reveal the effect of the absorption of NO molecules on the dielectric
propertiesof water clusters with different sizes, clusters are
divided into two groups. The first group consists of clusterscontaining two to ten
water molecules, while the second group contains from 11 to 20 H2O molecules. Six systemsof clusters are
studied, e.g., (H2O)n, and (NO)2(H2O)nwith 2≤n≤10 and 11≤n≤20 ranges. An
increase in the
cluster size in each group leads to the
amplification of absorption, reflection, and the power of emission of IR
radiation.The doubling of the NO concentration in the disperse
system results in weak changes in the absorption of IRradiation, reduces
the reflection and decreases the number of electrons participating in the
interaction with externalIR radiation, as well
as significantly lowers the power of thermal radiation emitted by the system.