The Spectral Characteristics of Chlorine_Containing Water Clusters in the Presence of Ozone and Oxygen
The Spectral Characteristics of Chlorine-Containing
Water Clusters in the Presence of Ozone and Oxygen
A. E. Galashev
Abstract—The
infrared absorption and Raman spectra were calculated by the molecular dynamics
method for water clusters with chlorine ions in a medium of water and ozone or
oxygen molecules. The intensity of IR absorption spectra of clusters with
absorbed oxygen increased and that of clusters with absorbed ozone decreased as
the number of chlorine ions grew. Excitation strengthening caused by an
increase in the number of Cl– ions weakened the intensity of Raman spectra
when either oxygen or ozone was absorbed; for ozone, this weakening was more
noticeable.
