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Главная » Статьи » 2009 » Rus J Phys Chem A

The Spectral Characteristics of Chlorine_Containing Water Clusters in the Presence of Ozone and Oxygen

The Spectral Characteristics of Chlorine-Containing Water Clusters in the Presence of Ozone and Oxygen


A. E. Galashev


Abstract—The infrared absorption and Raman spectra were calculated by the molecular dynamics method for water clusters with chlorine ions in a medium of water and ozone or oxygen molecules. The intensity of IR absorption spectra of clusters with absorbed oxygen increased and that of clusters with absorbed ozone decreased as the number of chlorine ions grew. Excitation strengthening caused by an increase in the number of Clions weakened the intensity of Raman spectra when either oxygen or ozone was absorbed; for ozone, this weakening was more noticeable.


Категория: Rus J Phys Chem A | Добавил: watercluster (18.03.2010)
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